In this work, the mechanisms for creating a combined electronic–radiative local state beneath the conduction band, consisting of intrinsic and activator electron–hole states, are experimentally substantiated. In the first part of this work, the mechanisms of the formation of intrinsic and activator electron–hole trapping centers are experimentally demonstrated in all four ...

In the present work, we investigate the potential of modified barium titanate (BaTiO3 ), an inexpensive perovskite oxide derived from earth-abundant precursors, for developing efficient water oxidation electrocatalysts using first-principles calculations. Based on our calculations, Rh doping is a way of making BaTiO3 absorb more light and have less overpotential needed for ...

This paper describes the desalination process by membrane distillation (MD) using track-etched membranes (TeMs). Hydrophobic track-etched membranes based on poly(ethylene terephthalate) (PET TeMs) with pore diameters from 700 to 1300 nm were prepared by UV-initiated graft polymerization of lauryl methacrylate (LMA) inside the nanochannels. Modified PET TeMs were investigated ...

By means of DFT oxygen evolution reaction on Rh-doped BaTiO3 (001) surface has been modeled. Gibbs free energies for each step of the reaction as well as the values of overpotential have been calculated, taking into account the solvation effect. The position of Rh-induces defect energy levels have been determined. Our findings indicated a substantial reduction in overpotential ...

Mutations in the human PARK7 gene that encodes protein DJ-1 lead to familial Parkinsonism due to loss of dopaminergic neurons. However, the molecular function of DJ-1 underpinning its cytoprotective effects are unclear. Recently, DJ-1 has been shown to prevent acylation of amino groups of proteins and metabolites by 1,3-bisphosphoglycerate. This acylation is indirect and ...

Developing novel membranes marks a significant advancement in flexible energy storage systems. In this work, a hybrid track-etched membrane (TeM) was synthesized through RAFT-mediated polymerization, where poly(acrylic acid) (PAA) was grafted onto both the nanopore walls and surface of PET-based TeMs (PET-g-PAA), creating a stable and functionalized matrix for further enhancements. ...

This research presents the results of conceptual design and modeling of an exoskeleton. It is intended for ankle joint rehabilitation in patients with musculoskeletal disorders. The exoskeleton design includes three screw actuators that smoothly control motion in the planes of dorsal and plantar flexion, inversion, and eversion. The results of the virtual tests performed on ...

This work describes the production of single crystals of the semiconducting quaternary compound Cu2ZnGeSe4 using a gas chemical method in which iodine was used as a transporter. For all the synthesized samples, their phase state, crystal structure syngony and lattice constants were refined. The unit cell of the studied compound is characterized by tetragonal symmetry. The ...

Composite track-etched membranes (CTeMs) emerged as a versatile and high-performance class of materials, combining the precise pore structures of traditional track-etched membranes (TeMs) with the enhanced functionalities of integrated nanomaterials. This review provides a comprehensive overview of the synthesis, functionalization, and applications of CTeMs. By incorporating ...

Cellulose-based sorbents are promising materials for wastewater treatment due to their environmental friendliness, biodegradability, and high sorption capacity. This paper presents an overview of cellulose modification methods, including carboxylation, amination, oxidation, graphene, and plasma treatments, as well as combined approaches. Their effect on key physicochemical ...