The Na2SO4 samples were obtained by slow evaporation method. The mechanisms of the formation of electron and hole trapping centers are investigated by spectroscopic methods. Intrinsic recombination emission of 2.9–3.1 eV and impurity emission of 1.85 eV are excited at 4.0–4.5 eV. Intrinsic SO3− 4 − SO−4 and impurity Mn+ − SO−4 trapping centers were revealed. The local levels ...

The nature of the impurity emission center and the energy transfer mechanisms from intrinsic electronic excitations to the Mn2+ impurity centers in the CaSO4 − Mn crystal have been investigated. The methods of vacuum ultraviolet, atomic absorption and luminescence spectroscopy are used in a wide temperature range from 5 K to 300 K. The energy transfer of intrinsic electronic ...

In the present work, the emission and excitation spectra in Li2SO4-Cu crystals have been obtained by the methods of vacuum-ultraviolet and thermoactivation spectroscopy. We have studied the nature of emission from a pressed and annealed sample of Li2SO4-Cu powders. It has been revealed that at low temperatures Cu0-SO−4-centers are formed during the trap of electrons by Cu+ ...

The mechanisms of creation of electron-hole trapping centers in LiKSO4 have been investigated by the methods of vacuum and thermal activation spectroscopy. It is shown that electron-hole trapping centers are formed during the trapping of electrons by anionic complexes and localization of a hole in the lattice in the form of the radical SO−4. The appearance of phosphorescence at ...

The nature of intrinsic emission and the creation of electron-hole trapping centers in irradiated with ultraviolet and X-rays at 15 K and 300 K was investigated in Li2SO4 by methods of spectroscopy. It is shown that in activated Li2SO4 with an energy of 6 ÷ 12.4 eV, emission appears in a wide spectral range to excite rare earth ions that are used as UV sources. These same photons ...

The methods of vacuum-ultraviolet and thermal activation spectroscopy were used to measure the excitation spectra of impurity radiation in the fundamental absorption band of K 2 SO 4 -Cu crystals at 15 K and 300 K. An energy transfer was detected from the base to Cu + impurities. The band gap of crystals K 2 SO 4 was estimated. In K 2 SO 4 -Cu crystals, recombination radiation ...

The mechanism of creation of electron-hole trapping centers in CaSO4 at 15-300 K was investigated by the methods of vacuum-ultraviolet and thermoactivation spectroscopy. It is shown that electron-hole trapping centers are formed upon trap of electrons in the anionic complexes SO2− 4 and localization of holes in the form of SO−4 radical. Based on the measurement of the spectrum ...

The Na2SO4 − Dy samples were obtained by slow evaporation method. The spectroscopic methods were used to study the mechanisms of formation of electron and hole trapping centers. Intrinsic recombination emission of 2.9–3.1 eV and impurity emission of 2.55 eV and 2.15 eV are excited at 4.0–4.5 eV. Intrinsic SO3−4 − SO−4 and impurity Dy2+ − SO−4 trapping centers were revealed. The ...