The synthesized SrSO4 crystalline powders were irradiated at photon energies from 6 ÷ 12 eV, in the temperature range from 15 ÷ 300 K. The investigation was carried out by the methods of atomic absorption, luminescence and vacuum ultraviolet spectroscopy. Intrinsic emissions were found at 3.7-3.8 eV, 4.2-4.6 eV and 4.9-5 eV, and long-wavelength recombination emissions at 2.6-2.7 ...