Bitumen-Biopolymer Materials Modified with Polylactic Acid with Improved Physical and Chemical Properties

Abstract

With the continuous expansion of the global automobile fleet, there is an escalating demand to enhance and maintain current road infrastructure. Given the information provided, there will be a growing demand for bitumen, a key raw material used in the manufacturing of asphalt. Bitumen may account for up to 60% of the total usage in asphalt production. This study aims to determine the effect of different content of polylactic acid (PLA) on the change in the chemical and physical properties of biopolymer bitumen during its modification. This study was carried out by using a sample of petroleum road bitumen from CASPI BITUM (Kazakhstan) and a sample of PLA from Zhejiang Hisun (China). As a part of the research, the change of quality indicators of biopolymer bitumen when adding 4%–10% of PLA to it has been established. The results showed that the values of the average molecular weight and average molar mass increased with increasing the content of PLA in biopolymer bitumen. In particular, when the PLA content in biopolymer bitumen increased up to 10%, the average molecular weight of the biopolymer bitumen increased from 1,263 to 2,759 Mw and the average molar mass increased from 1,215 to 1,395 Mn. It was shown that increasing the PLA content in biopolymer bitumen from 0% to 10% leads to an increase in the softening temperature from 47 to 70°C or ∼49%. It was found that all examined samples of biopolymer bitumen are characterized by increased plasticity at 25°C (>100 cm). It has been established that the addition of 8% PLA to bitumen allows one to obtain a biopolymer bitumen of optimal quality. The results obtained can be used to produce road biopolymer bitumen.