Abstract:
In this paper, we consider the possibility of a fundamental measurement of the absolute
values of electrode potentials using probes - small electrodes, is positioned within the electrolyte
through which electric current flows. Getting the probe characteristics in the case of electrolyte
solutions is a promising method for direct measurement of both equilibrium and non-equilibrium
characteristics of double layers formed at the metal-electrolyte interface. The theoretical and
experimental problems to be solved in the sequential development of methods of measuring probe
of the absolute values of electrode potentials.
